KMID : 1059519880320030276
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Journal of the Korean Chemical Society 1988 Volume.32 No. 3 p.276 ~ p.284
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Copolyester Studies VIII. Crystallization Behaviours of Poly(ethylene terephthalate) Modified by the Flexible Diol Unit
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Ahn Tae-Oan
Kim Jung-Ho Jeong Han-Mo
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Abstract
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The crystallization behaviours of poly(ethylene terephthalate) modified by 1, 3-propane diol, 1, 5-pentane diol, 1, 6-hexane diol, or poly(ethylene glycol) of molecular weight 300 as a third component were studied by isothermal and nonisothermal crystallization. When the content of the third diol was about 4 mol %, the isothermal crystallization rate at the same supercooling below the melting temperature and the nonisothermal crystallization rate at the same overheating above the glass transition temperature were increased more by the shorter flexible diol unit. On the contrary the nonisothermal crystallization rate at the same supercooling below the melting temperature was increased more by the longer flexible diol unit.
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